{ "schemaVersion": 1, "title": "Electrical operating points in the matched Hu OLED series", "question": "How much electrical input accompanies each measured light-output point, and which published efficiency columns are internally consistent?", "source": { "id": "hu-2022-figure3", "doi": "10.1038/s41566-022-01083-y", "title": "Efficient selenium-integrated TADF OLEDs with reduced roll-off", "url": "https://www.nature.com/articles/s41566-022-01083-y", "workbookUrl": "https://media.springernature.com/original/springer-static/esm/art%3A10.1038%2Fs41566-022-01083-y/MediaObjects/41566_2022_1083_MOESM3_ESM.xls", "workbookSha256": "d076c92b3ea8487e23c5f88ba77229e663d859d48fb17dddd13195e8594837aa", "workbookBytes": 51395, "accessed": "2026-09-26", "locators": [ "Fig. 3d: voltage, current density and luminance", "Fig. 3e: luminance and EQE", "Fig. 3f: luminance, current efficiency and power efficiency" ], "originalRedistributed": false, "reuse": "Numerical observations extracted and attributed to Hu et al. The rights-reserved publisher workbook and article are not redistributed. No CC licence is asserted for the original workbook." }, "methodSource": { "doi": "10.1002/adom.202000838", "title": "Accurate Efficiency Measurements of Organic Light-Emitting Diodes via Angle-Resolved Spectroscopy", "authors": "Archer et al.", "year": 2021, "url": "https://advanced.onlinelibrary.wiley.com/doi/10.1002/adom.202000838", "locator": "Sections 4–5: forward luminance versus angle-integrated flux; luminous efficacy definition and angular correction.", "use": "Primary measurement-method reference for distinguishing forward current efficiency from angle-integrated photometric efficacy. No experimental numbers transferred to the Hu devices." }, "conditions": { "summary": "Hu et al. 2022 devices A–D; vacuum-deposited common stack; 1 wt% emitter in DMIC-TRZ, 50 nm emitting layer.", "host": "DMIC-TRZ", "emitterLoadingWtPercent": 1, "emittingLayerThicknessNm": 50, "stack": [ { "name": "ITO", "thicknessNm": null, "role": "Transparent anode" }, { "name": "HAT-CN", "thicknessNm": 5, "role": "Hole injection" }, { "name": "TAPC", "thicknessNm": 30, "role": "Hole transport" }, { "name": "TCTA", "thicknessNm": 15, "role": "Hole transport" }, { "name": "mCBP", "thicknessNm": 10, "role": "Electron/exciton confinement" }, { "name": "DMIC-TRZ + 1 wt% emitter", "thicknessNm": 50, "role": "Emitting layer" }, { "name": "POT2T", "thicknessNm": 20, "role": "Hole/exciton confinement" }, { "name": "ANT-BIZ", "thicknessNm": 30, "role": "Electron transport" }, { "name": "Liq", "thicknessNm": null, "role": "Electron injection" }, { "name": "Al", "thicknessNm": null, "role": "Cathode" } ], "stackSource": "Hu et al. 2022 final Figure 3a and device-architecture paragraph; SI Table 9 independently confirms 1 wt% loading for device D.", "thicknessNote": "Liq and Al thicknesses are not shown in the final figure; omitted rather than taking numbers from an earlier preprint. ITO thickness not specified here.", "emittingAreaCm2Approximate": 0.09, "measurement": "Keithley 2400 source meter and Hamamatsu C9920-12 absolute EQE measurement system.", "measurementSource": "Supporting information, Device performances, printed page 29 (PDF page 30).", "measurementSourceUrl": "https://media.springernature.com/original/springer-static/esm/art%3A10.1038%2Fs41566-022-01083-y/MediaObjects/41566_2022_1083_MOESM1_ESM.pdf", "pointwiseUncertainty": null, "pointwiseUncertaintyNote": "No per-point uncertainties or repeated JVL sweeps are supplied in this Figure 3 source workbook. Ensemble peak-EQE statistics from another table are not uncertainty bands for these points." }, "materials": [ { "materialId": "bnoo", "studyDevice": "A", "label": "BNOO", "emitterName": "2PXZBN" }, { "materialId": "bnss", "studyDevice": "B", "label": "BNSS", "emitterName": "2PTZBN" }, { "materialId": "bnsse", "studyDevice": "C", "label": "BNSSe", "emitterName": "BNSSe" }, { "materialId": "bnsese", "studyDevice": "D", "label": "BNSeSe", "emitterName": "BNSeSe" } ], "definitions": { "electricalPowerDensityMwCm2": "voltageV * currentDensityMaCm2; mW cm^-2", "electricalPowerDensityWm2": "10 * voltageV * currentDensityMaCm2; W m^-2", "calculatedCurrentEfficiencyCdA": "luminanceCdM2 / (10 * currentDensityMaCm2); cd A^-1", "lambertianLuminousEfficacyLmW": "pi * luminanceCdM2 / (10 * currentDensityMaCm2 * voltageV); lm W^-1, conditional on Lambertian angular emission", "reportedLuminousEfficacyLmW": "The numerical Fig. 3f Power efficiency [lm/W] column, renamed to make its photometric dimension clear; preserved unchanged.", "nearestPoint": "Select the observed luminance minimizing absolute difference from the target; break ties toward lower luminance. The returned actual brightness need not equal the target." }, "protocol": { "join": "Within each device, join the stored luminance values across Fig. 3d/e/f by exact Decimal equality. Sheet row index is not a join key. Require exactly one matching EQE and efficiency row.", "displayDomain": "Luminance >= 1 cd m^-2, positive voltage and current density, physically bounded source EQE (0–100%). Preserve all raw numerical rows in CSV, including low-signal artifacts.", "interpolation": "None. Source rows outside the available JVL sweep cannot acquire inferred voltage/current.", "roundingCheck": "For the source CE versus V*PE/pi identity, use half of the least stored decimal unit in each source CE/PE cell, treating V as the nominal sweep setting. These intervals diagnose arithmetic consistency only, not experimental uncertainty.", "rawPrecision": "The original XML numeric strings are retained in CSV; values are not rounded again.", "powerRoundingCheck": "PE versus JVL additionally propagates half-last-stored-unit rounding in J and L. One D point at8.4 V narrowly misses single-pass rounding; allowing one additional CE-intermediate rounding covers it. This is a numerical consistency bound, not experimental uncertainty or a claim about the original calculation pipeline." }, "limits": [ "Each selection is a real sweep point. The nearest point to a requested brightness is labelled with its actual measured luminance; it is not an interpolated operating point.", "Different devices at the same voltage, or at their separate nearest brightness points, are not necessarily at equal light output or equal exciton density.", "The lm/W column is photometric luminous efficacy, not a dimensionless electrical-to-optical energy efficiency. Colour and angular emission affect it.", "The pi conversion assumes Lambertian emission. Agreement with the stored power-efficiency column is an arithmetic check; it does not establish an angular calibration for these OLEDs.", "The matched series supports descriptive comparisons; a bipolar OLED JVL curve alone does not identify charge mobility, injection barriers, charge balance, annihilation rate, or the cause of efficiency loss.", "No pointwise experimental uncertainties are available in this workbook. Numerical residuals and source-cell rounding intervals are not measurement error bars.", "Device C has inconsistent source current-efficiency entries at 10.0 and 10.4 V. 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