蔗糖

一种二糖，葡萄糖和果糖的异头碳均参与成键。

化学式
C12H22O11
摩尔质量
342.3 g/mol
Also known as
(2R,3R,4S,5S,6R)-2-[(2S,3S,4S,5R)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol, saccharose, sugar, Table sugar, Cane sugar, White sugar, Saccharum

概览

The glycosidic bond involves both anomeric centres, preventing ordinary ring opening to a free carbonyl at either end. Sucrose is therefore non-reducing in the standard classification. Hydrolysis releases glucose and fructose, changing the chemistry of the resulting mixture.

Identifiers

化学式
C12H22O11
摩尔质量
342.3 g/mol
Also known as
(2R,3R,4S,5S,6R)-2-[(2S,3S,4S,5R)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol, saccharose, sugar, Table sugar, Cane sugar, White sugar, Saccharum
化学标识符
SMILES
C([C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)O[C@]2([C@H]([C@@H]([C@H](O2)CO)O)O)CO)O)O)O)O
InChI
InChI=1S/C12H22O11/c13-1-4-6(16)8(18)9(19)11(21-4)23-12(3-15)10(20)7(17)5(2-14)22-12/h4-11,13-20H,1-3H2/t4-,5-,6-,7-,8+,9-,10+,11-,12+/m1/s1
PubChem CID
5988

性质

熔点
185.5 °C
沸腾／分解
Decomposes (NTP, 1992)
密度
1.5805 g/cu cm @ 17 °C
水中溶解度
water solubility = 2.12X10+6 mg/l @ 25 °C

参考文献

  1. PubChem Compound Summary: Sucrose (CID 5988)National Center for Biotechnology Information · PubChem

    Identity, molecular formula, molecular weight and aliases retrieved via PUG REST on 2026-09-08.

  2. OpenStax Organic Chemistry: DisaccharidesJohn McMurry · OpenStax · 2023

    Supports the qualitative structural interpretation of the recorded molecular structure; no new physical measurement or verified preparative yield is claimed.

  3. Hazardous Substances Data Bank (HSDB): Sucrose — melting pointHazardous Substances Data Bank (HSDB)

    Retrieved through PubChem PUG View on 2026-09-08. https://pubchem.ncbi.nlm.nih.gov/compound/5988#section=Melting-Point. Source value, complete property clause or compact miscibility statement retained; absent pressure, temperature or phase conditions are not inferred. Original reference: Lide, D.R. (ed.). CRC Handbook of Chemistry and Physics. 79th ed. Boca Raton, FL: CRC Press Inc., 1998-1999., p. 3-172

  4. CAMEO Chemicals: Sucrose — boiling pointCAMEO Chemicals

    Retrieved through PubChem PUG View on 2026-09-08. https://pubchem.ncbi.nlm.nih.gov/compound/5988#section=Boiling-Point. Source value, complete property clause or compact miscibility statement retained; absent pressure, temperature or phase conditions are not inferred. Original reference: National Toxicology Program, Institute of Environmental Health Sciences, National Institutes of Health (NTP). 1992. National Toxicology Program Chemical Repository Database. Research Triangle Park, North Carolina.

  5. Hazardous Substances Data Bank (HSDB): Sucrose — densityHazardous Substances Data Bank (HSDB)

    Retrieved through PubChem PUG View on 2026-09-08. https://pubchem.ncbi.nlm.nih.gov/compound/5988#section=Density. Source value, complete property clause or compact miscibility statement retained; absent pressure, temperature or phase conditions are not inferred. Original reference: Lide, D.R. (ed.). CRC Handbook of Chemistry and Physics. 79th ed. Boca Raton, FL: CRC Press Inc., 1998-1999., p. 3-172

  6. Hazardous Substances Data Bank (HSDB): Sucrose — solubilityHazardous Substances Data Bank (HSDB)

    Retrieved through PubChem PUG View on 2026-09-08. https://pubchem.ncbi.nlm.nih.gov/compound/5988#section=Solubility. Source value, complete property clause or compact miscibility statement retained; absent pressure, temperature or phase conditions are not inferred. Original reference: Yalkowsky SH, Dannenfelser RM; The AQUASOL dATAbASE of Aqueous Solubility. Fifth Ed, Tucson, AZ: Univ Az, College of Pharmacy (1992)