叔醇
格氏试剂与酮加成，再经酸性后处理，可生成叔醇。
- 官能团
- R3COH
- Also known as
- 叔醇
概览
Alcohols where the carbon bearing OH is attached to three carbon groups.
A tertiary alcohol has three carbon groups and no hydrogen on its OH-bearing carbon. It resists the ordinary oxidation conditions used to distinguish primary and secondary alcohols. Acid-catalysed dehydration can still form an alkene when an adjacent carbon provides a removable hydrogen.
Identifiers
- 官能团
- R3COH
- Also known as
- 叔醇
化学标识符
- SMILES
- CC(C)(C)O
性质
- 氧化试验阴性结果
- 叔醇在给定条件下保持重铬酸盐原有颜色。
- 反应选择
- 耐氧化性与酸催化脱水，是同一分子的两种不同反应性质。
Related compounds
- 2-甲基-2-丙醇
一种叔醇，可与伯醇、仲醇的氧化反应进行对比。
Connected reactions
- Carbonyl addition: Grignard reagents → Tertiary alcohols
格氏试剂与酮加成，经后处理得到叔醇。
- Grignard addition co reactant: Ketones → Tertiary alcohols
酮与格氏试剂反应，经酸性后处理得到叔醇。
参考文献
- Organic Chemistry: Oxidation of AlcoholsJohn McMurry · OpenStax Organic Chemistry · 2023
Supports functional-group chemistry used to curate the linked examples. Checked 2026-09-16; named examples are applications of textbook scope, without claimed experimental yields.
- PubChem Compound Summary: 2-Methylpropan-2-ol (CID 6386)National Center for Biotechnology Information · PubChem
Identity, molecular formula, molecular weight and aliases retrieved via PUG REST on 2026-09-08.